Synthesis and Aggregation Studies of Bingel-Hirsch Monoadducts of Gadofullerene
| العنوان: | Synthesis and Aggregation Studies of Bingel-Hirsch Monoadducts of Gadofullerene |
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| المؤلفون: | Jinhua Liu, Rui He, Xia Li, Hong Zhao, Liang Yuanyuan, Chen Canyu, Yanhua Jiao |
| المصدر: | Fullerenes, Nanotubes and Carbon Nanostructures. 21:549-559 |
| بيانات النشر: | Informa UK Limited, 2013. |
| سنة النشر: | 2013 |
| مصطلحات موضوعية: | Chemistry, Organic Chemistry, Mass spectrometry, High-performance liquid chromatography, Atomic and Molecular Physics, and Optics, chemistry.chemical_compound, Matrix-assisted laser desorption/ionization, Malonate, Dynamic light scattering, Yield (chemistry), Polymer chemistry, Organic chemistry, General Materials Science, Bingel reaction, Physical and Theoretical Chemistry, Fourier transform infrared spectroscopy |
| الوصف: | The monoadducted malonic ester derivative of paramagnetic gadofullerene, Gd@C82[C(COOCH2CH3)2], was synthesized by the Bingel reaction, which Gd@C82 was reacted with diethyl bromomalonate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. It was isolated and purified by high performance liquid chromatography, and subsequently hydrolyzed to yield water-soluble disodium salt form Gd@C82[C(COONa)2] by the Hirsch reaction. The disodium salt was purified by dialysis. The resulting materials were characterized by various measurements, such as matrix assisted laser desorption ionization time-of-flight mass spectrometry, ultraviolet-visible near-infrared and fourier transform infrared spectroscopy. The aggregation behavior of the newly water-soluble nanoparticles was investigated by scanning electron microscopy and dynamic light scattering analysis. This presented synthetic methodology opens the avenue for the preparation of novel water-soluble malonate derivatives of paramagnetic Gd@C82, which are expected t... |
| تدمد: | 1536-4046 1536-383X |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::5a4eafea9a460691f4a1782acd90ac60 https://doi.org/10.1080/1536383x.2011.643423 |
| رقم الأكسشن: | edsair.doi...........5a4eafea9a460691f4a1782acd90ac60 |
| قاعدة البيانات: | OpenAIRE |
PDF full text from Publisher | تدمد: | 15364046 1536383X |
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