Cobalt, nickel, and copper salicylaldoxime compounds at high pH's: Behaviour, composition, and structure

التفاصيل البيبلوغرافية
العنوان: Cobalt, nickel, and copper salicylaldoxime compounds at high pH's: Behaviour, composition, and structure
المؤلفون: M. Bobtelsky, E. Jungreis
المصدر: Journal of Inorganic and Nuclear Chemistry. 3:38-48
بيانات النشر: Elsevier BV, 1956.
سنة النشر: 1956
مصطلحات موضوعية: Nickel, Copper salicylaldoxime, Ammonia, chemistry.chemical_compound, Polymers and Plastics, chemistry, Inorganic chemistry, Materials Chemistry, chemistry.chemical_element, Cobalt metal, Composition (visual arts), Cobalt, Copper
الوصف: The only cobalt complex which is formed at pH's 6–8 is soluble and has the composition [Co 2 III (SAO) 3 ] 0 . With nickel, an insoluble complex [Ni(SAO) 2 ] 0 is formed quantitatively between pH = 6 ⩽ 12. At pH ≥ 12 it is abruptly and completely transformed into the soluble complex [Ni(SAO) 2 2− . K = [Ni 2+ ] [SAO] 2 /[Ni(SAO) 2 −2 ] = 6·4 × 10 −5 . With copper, the insoluble complex [Cu(SAO) 2 ] 0 is quantitavely formed between pH 3–10, and it is completely and abruptly transformed into [Cu(SAO) 2 ] 2− which is soluble, at pH ≥ 11. K = [Cu 2+ ] [SAO 2− ] 2 /[Cu(SAO) 2 −2 ] = 6·4 × 10 −5 . Ammonia does not interfere with the soluble complexes.
تدمد: 0022-1902
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::642aa7841ec34733e9b138e277f9a3ac
https://doi.org/10.1016/0022-1902(56)80112-7
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........642aa7841ec34733e9b138e277f9a3ac
قاعدة البيانات: OpenAIRE