The average Pd oxidation state in Pd/SiO2 quantified by L3-edge XANES analysis and its effects on catalytic activity for CO oxidation
| العنوان: | The average Pd oxidation state in Pd/SiO2 quantified by L3-edge XANES analysis and its effects on catalytic activity for CO oxidation |
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| المؤلفون: | Ken-ichi Shimizu, Atsushi Satsuma, Kaoru Osaki, Hisao Yoshida, Yuichi Kamiya |
| المصدر: | Catalysis Science & Technology. 2:767 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2012. |
| سنة النشر: | 2012 |
| مصطلحات موضوعية: | Chemistry, Analytical chemistry, chemistry.chemical_element, Catalysis, Spectral line, XANES, Metal, Oxidation state, visual_art, visual_art.visual_art_medium, Molecule, Absorption (chemistry), Palladium |
| الوصف: | The palladium oxidation state of an SiO2-supported palladium catalyst was quantitatively determined by Pd L3-edge XANES (X-ray absorption near-edge structure) analysis. By changing the time of CO-reduction pre-treatment at 673 K, a series of 5 wt% Pd-loaded SiO2 catalysts (PdOx/2/SiO2) containing different amounts of the Pd metal and PdO phases were prepared, and the average oxidation number (x) was estimated from the number of CO2 molecules formed during the CO-reduction treatment. L3-edge XANES spectra of these samples and a reference sample (Pd powder) were recorded, and the white line area of the spectra was evaluated. A good linear relationship was confirmed between the white line area intensity and the average oxidation number (x), indicating that the oxidation state of Pd in structurally unknown Pd samples could be quantitatively determined by a simple XANES analysis. To demonstrate the utility of this method in a catalytic study, the effect of the oxidation number (x) on the CO oxidation activity of PdOx/2/SiO2 was also examined, and metallic Pd0 sites in PdOx/2/SiO2 were shown to be active species. |
| تدمد: | 2044-4761 2044-4753 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::6bd94f63c252bafcf1bbb04cae03c057 https://doi.org/10.1039/c2cy00422d |
| رقم الأكسشن: | edsair.doi...........6bd94f63c252bafcf1bbb04cae03c057 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 20444761 20444753 |
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