A Pd II Carbene Complex with Anthracene Side‐Arms for π‐Stacking on Reduced Graphene Oxide (rGO): Activity towards Undirected C–H Oxygenation of Arenes
| العنوان: | A Pd II Carbene Complex with Anthracene Side‐Arms for π‐Stacking on Reduced Graphene Oxide (rGO): Activity towards Undirected C–H Oxygenation of Arenes |
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| المؤلفون: | Ola F. Wendt, Payam Shayesteh, Joachim Schnadt, Maitham H. Majeed, L. Reine Wallenberg, Axel R. Persson |
| المصدر: | European Journal of Inorganic Chemistry. 2018:4742-4746 |
| بيانات النشر: | Wiley, 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | Anthracene, 010405 organic chemistry, Graphene, Stacking, Oxide, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Catalysis, law.invention, Inorganic Chemistry, chemistry.chemical_compound, chemistry, law, Polymer chemistry, Benzene, Carbene, Palladium |
| الوصف: | An N-heterocyclic carbene palladium(II) complex containing two anthracene side arms was immobilized on the surface of reduced graphene oxide (rGO) by π-stacking. The activity of the homogeneous analogue and the supported complex in undirected C–H acetoxylation reaction of arenes was studied. The results show that the catalytic efficiency in acetoxylation of benzene is improved in the immobilized materials compared to the homogeneous analogue. According to XPS analysis, the immobilized catalyst maintains the original oxidation state of PdII after the catalytic reaction. |
| تدمد: | 1099-0682 1434-1948 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::77d03208d445d721f6f28fc2be13b908 https://doi.org/10.1002/ejic.201800978 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........77d03208d445d721f6f28fc2be13b908 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10990682 14341948 |
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