ChemInform Abstract: Ascorbic Acid Chemistry. A Novel LiAlH4 Reduction Product and Its Rearrangement
| العنوان: | ChemInform Abstract: Ascorbic Acid Chemistry. A Novel LiAlH4 Reduction Product and Its Rearrangement |
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| المؤلفون: | Ping Wang, Louise H. Foley |
| المصدر: | ChemInform. 30 |
| بيانات النشر: | Wiley, 2010. |
| سنة النشر: | 2010 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Hydride, Chemistry, Diol, Michael reaction, General Medicine, Allylic alcohol, Ascorbic acid, Medicinal chemistry |
| الوصف: | Reaction of 1 with LiAlH4 affords the chiral monobenzyloxy diol, 5(S), 6-0-isopropylidene-4(R)-hydroxyl-2-benzyloxy-2-hexenol. Evidence is provided to support a mechanism involving Michael addition of hydride to C-3. Reduction products, 2 & 3, undergo facile allylic alcohol rearrangements. |
| تدمد: | 1522-2667 0931-7597 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::79a929be60ed2a1f783e5e32eb31ab31 https://doi.org/10.1002/chin.199935263 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........79a929be60ed2a1f783e5e32eb31ab31 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15222667 09317597 |
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