A Triazolate-Supported Fe3(μ 3 -O) Core: Crystal Structure, Fluorescence, and Hirshfeld Surface Analysis
| العنوان: | A Triazolate-Supported Fe3(μ 3 -O) Core: Crystal Structure, Fluorescence, and Hirshfeld Surface Analysis |
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| المؤلفون: | Hong Zhao, Yu-Qing Zhu, Chao Feng, Xue Xingying |
| المصدر: | Journal of Cluster Science. 27:1181-1190 |
| بيانات النشر: | Springer Science and Business Media LLC, 2016. |
| سنة النشر: | 2016 |
| مصطلحات موضوعية: | 010405 organic chemistry, Hydrogen bond, Chemistry, Nanochemistry, Infrared spectroscopy, General Chemistry, Crystal structure, 010402 general chemistry, Condensed Matter Physics, 01 natural sciences, Biochemistry, Fluorescence, 0104 chemical sciences, Catalysis, Crystallography, Cluster (physics), Hydrothermal synthesis, General Materials Science |
| الوصف: | One new trinuclear Fe(III) cluster with a Fe3(μ 3-O) core was synthesized by the method of hydrothermal synthesis. The complex [Fe3(μ 3-O)(pmta)6(H2O)3]FeCl4·2H2O (1) (where Hpmta is 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid) was characterized by single-crystal X-ray diffraction methods, elemental analyses, IR spectroscopy, fluorescence and Hirshfeld surface analysis. For complex 1, the crystal structure is extended into 3D structure through N–H···O and O–H···O hydrogen bonds. According to the 3D Hirshfeld surface and 2D fingerprint plots, the main interactions in the cluster are the H···H, N···H and C···H contacts. |
| تدمد: | 1572-8862 1040-7278 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::80724119993904aef69ff2a25b62b15b https://doi.org/10.1007/s10876-016-0989-8 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........80724119993904aef69ff2a25b62b15b |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 15728862 10407278 |
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