Electronic Structure of EuMo6Se8 Studied by X-Ray Absorption Spectroscopy
| العنوان: | Electronic Structure of EuMo6Se8 Studied by X-Ray Absorption Spectroscopy |
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| المؤلفون: | K. Asokan, J. W. Chiou, Way-Faung Pong, Octavio Peña, L. Le Polles, J. C. Jan |
| المصدر: | Journal of Cluster Science. 20:205-211 |
| بيانات النشر: | Springer Science and Business Media LLC, 2008. |
| سنة النشر: | 2008 |
| مصطلحات موضوعية: | X-ray absorption spectroscopy, Valence (chemistry), Chemistry, Magnetism, Valency, General Chemistry, Electronic structure, Crystal structure, Condensed Matter Physics, Biochemistry, XANES, Condensed Matter::Materials Science, Crystallography, General Materials Science, Spectroscopy |
| الوصف: | The rare-earth based molybdenum chalcogenides, REMo6Se8 (RE = rare-earth metals) have been extensively studied because of their unique crystal structure based on Mo6Se8 clusters and their outstanding properties involving coexistence of superconductivity and magnetism. Among all these compounds, Ce and Eu based chalcogenides are magnetic and non-superconductors and possess many novel properties. Understanding their electronic structure is likely to provide valuable information about these materials. We employ X-ray absorption near-edge structure (XANES) spectroscopy at Mo and Se K-edges of EuMo6Se8 to identify the local environment respectively around Mo and Se ions and XANES spectra at L3-edge of Eu ion to identify their valence state. Results from this study demonstrate that Se ions in EuMo6Se8 are in two inequivalent sites and the valency of Eu is divalent. |
| تدمد: | 1572-8862 1040-7278 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::80de5a716d7541a918b32f7e12f44ceb https://doi.org/10.1007/s10876-008-0220-7 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........80de5a716d7541a918b32f7e12f44ceb |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 15728862 10407278 |
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