A new approach to the surface plasma resonance of small metal particles
| العنوان: | A new approach to the surface plasma resonance of small metal particles |
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| المؤلفون: | Muliang Xu, Michael J. Dignam |
| المصدر: | The Journal of Chemical Physics. 96:3370-3378 |
| بيانات النشر: | AIP Publishing, 1992. |
| سنة النشر: | 1992 |
| مصطلحات موضوعية: | Electron density, Condensed matter physics, Polarizability, Chemistry, Differential equation, Surface plasmon, Jellium, General Physics and Astronomy, Dielectric, Physical and Theoretical Chemistry, Drude model, Molecular physics, Plasmon |
| الوصف: | A differential equation for the polarizability of a small, continuum, spherically symmetric medium is developed in the local‐dielectric‐response approximation. The dynamic polarizability of a small metal sphere is then calculated through this equation using the Drude dielectric expression with the spatial dispersion of the free electron density given by the results of self‐consistent density functional calculations on jellium. This approach is used to examine the size dependence of the plasmon resonance absorption of small metal particles. It is able to account for the observed broadening and peak frequency shifts, both ‘‘red’’ and ‘‘blue,’’ as well as the additional absorption feature seen for small particles. To the extent that comparison with experimental data is possible, good agreement is found. |
| تدمد: | 1089-7690 0021-9606 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::82a58f199c3323349adc8389f7e4f9c4 https://doi.org/10.1063/1.461938 |
| رقم الأكسشن: | edsair.doi...........82a58f199c3323349adc8389f7e4f9c4 |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Scitation. | تدمد: | 10897690 00219606 |
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