Immobilized iodosobenzoate catalysts for the cleavage of reactive phosphates
| العنوان: | Immobilized iodosobenzoate catalysts for the cleavage of reactive phosphates |
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| المؤلفون: | Yong Chan Chung, Robert A. Moss |
| المصدر: | The Journal of Organic Chemistry. 55:2064-2069 |
| بيانات النشر: | American Chemical Society (ACS), 1990. |
| سنة النشر: | 1990 |
| مصطلحات موضوعية: | inorganic chemicals, Aqueous solution, Organic Chemistry, Kinetics, Inorganic chemistry, Substrate (chemistry), Cleavage (embryo), Catalysis, chemistry.chemical_compound, chemistry, Reagent, Polymer chemistry, Titanium dioxide, Bond cleavage |
| الوصف: | Titanium dioxide and nylon covalently supported iodosobenzoate reagents 11 and 19 have been prepared. Both 11 and 19 are good catalysts for the cleavage of p-nitrophenyl diphenyl phosphate (PNPDPP) under heterogeneous aqueous conditions at pH 8. The kinetics of the cleavage reactions have been characterized in the presence of excess substrate (turnover conditions), and in the presence of dilute cetyltrimethylammonium chloride, which enhances both PNPDPP cleavage and catalyst turnover |
| تدمد: | 1520-6904 0022-3263 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::87d488edfd4190252cb5b5ef3f842e93 https://doi.org/10.1021/jo00294a019 |
| رقم الأكسشن: | edsair.doi...........87d488edfd4190252cb5b5ef3f842e93 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15206904 00223263 |
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