Synthesis, characterization and fluorescence quenching of poly(fluorene-alt-enylenevinylene)s

التفاصيل البيبلوغرافية
العنوان: Synthesis, characterization and fluorescence quenching of poly(fluorene-alt-enylenevinylene)s
المؤلفون: Jian-hua Xiao, Jun Hu, Honglai Liu, Feng Liu, Hai-li Chen
المصدر: Frontiers of Materials Science in China. 2:409-416
بيانات النشر: Springer Science and Business Media LLC, 2008.
سنة النشر: 2008
مصطلحات موضوعية: chemistry.chemical_classification, Materials science, Photoluminescence, Condensation polymer, Polymer, Fluorene, Conjugated system, Photochemistry, Fluorescence, chemistry.chemical_compound, chemistry, Polymer chemistry, Nitro, General Materials Science, Spectroscopy
الوصف: Two poly(fluorine-alt-phenylenevinylene)s fluorescent conjugated polymers, poly(9,9-dioctylfluorene-alt-phenylenevinylene) (PFO/PPV1) and poly (fluorene-alt-2,5-dioctoxyphenylenevinylene) (PFO/PPV2), were obtained through a Heck polycondensation. The structures of the obtained polymers were characterized by FT-IR, 1H-NMR and GPC. The thermal stabilities of the polymers were evaluated by TGA. The photophysical properties were studied by UV and photoluminescence (PL) spectroscopy both in solution and film. Their applications in the detection of nitro compounds were researched, and the results show high fluorescence quenching sensitivity of PFO/PPV1 towards nitro compounds such as 2,4-dinitrotoluene (DNT) and 4-nitrotoluene (p-NT) in solution and thin film.
تدمد: 1673-7482
1673-7377
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::891cb5d2f4fca974fed0e19a5ccb3c58
https://doi.org/10.1007/s11706-008-0069-6
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........891cb5d2f4fca974fed0e19a5ccb3c58
قاعدة البيانات: OpenAIRE