Synthesis, characterization and fluorescence quenching of poly(fluorene-alt-enylenevinylene)s
العنوان: | Synthesis, characterization and fluorescence quenching of poly(fluorene-alt-enylenevinylene)s |
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المؤلفون: | Jian-hua Xiao, Jun Hu, Honglai Liu, Feng Liu, Hai-li Chen |
المصدر: | Frontiers of Materials Science in China. 2:409-416 |
بيانات النشر: | Springer Science and Business Media LLC, 2008. |
سنة النشر: | 2008 |
مصطلحات موضوعية: | chemistry.chemical_classification, Materials science, Photoluminescence, Condensation polymer, Polymer, Fluorene, Conjugated system, Photochemistry, Fluorescence, chemistry.chemical_compound, chemistry, Polymer chemistry, Nitro, General Materials Science, Spectroscopy |
الوصف: | Two poly(fluorine-alt-phenylenevinylene)s fluorescent conjugated polymers, poly(9,9-dioctylfluorene-alt-phenylenevinylene) (PFO/PPV1) and poly (fluorene-alt-2,5-dioctoxyphenylenevinylene) (PFO/PPV2), were obtained through a Heck polycondensation. The structures of the obtained polymers were characterized by FT-IR, 1H-NMR and GPC. The thermal stabilities of the polymers were evaluated by TGA. The photophysical properties were studied by UV and photoluminescence (PL) spectroscopy both in solution and film. Their applications in the detection of nitro compounds were researched, and the results show high fluorescence quenching sensitivity of PFO/PPV1 towards nitro compounds such as 2,4-dinitrotoluene (DNT) and 4-nitrotoluene (p-NT) in solution and thin film. |
تدمد: | 1673-7482 1673-7377 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::891cb5d2f4fca974fed0e19a5ccb3c58 https://doi.org/10.1007/s11706-008-0069-6 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........891cb5d2f4fca974fed0e19a5ccb3c58 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 16737482 16737377 |
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