The in Situ NHC-Palladium Catalyzed Selective Activation of B(3)–H or B(6)–H Bonds of o-Carboranes for Hydroboration of Alkynes: An Efficient Approach to Alkenyl-o-carboranes
| العنوان: | The in Situ NHC-Palladium Catalyzed Selective Activation of B(3)–H or B(6)–H Bonds of o-Carboranes for Hydroboration of Alkynes: An Efficient Approach to Alkenyl-o-carboranes |
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| المؤلفون: | Xin-Yu Wen, Cai-Yan Zhang, Tao-Tao Xu, Ke Cao, Junxiao Yang, Ji Wu |
| المصدر: | Inorganic Chemistry. 60:1080-1085 |
| بيانات النشر: | American Chemical Society (ACS), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | In situ, 010405 organic chemistry, Chemistry, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, 0104 chemical sciences, Catalysis, Inorganic Chemistry, Hydroboration, Surface modification, Physical and Theoretical Chemistry, Palladium |
| الوصف: | An in situ Pd-NHC catalyzed selective B(3,6)-H activation for hydroboration of internal alkynes has been accomplished under mild conditions. This work offers a facile approach for the synthesis of alkenyl-o-carboranes and has important reference for selective functionalization of B(3,6)-H bonds. |
| تدمد: | 1520-510X 0020-1669 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::8c347b33172c0f548acae865c07ee7d3 https://doi.org/10.1021/acs.inorgchem.0c03203 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........8c347b33172c0f548acae865c07ee7d3 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 1520510X 00201669 |
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