Absorption of nitric oxide promoted by strong oxidizing agents: organic tertiary hydroperoxides in n-hexadecane
| العنوان: | Absorption of nitric oxide promoted by strong oxidizing agents: organic tertiary hydroperoxides in n-hexadecane |
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| المؤلفون: | Howard D. Perlmutter, Henry Shaw, Huihong Ao |
| المصدر: | Environmental Science & Technology. 27:128-133 |
| بيانات النشر: | American Chemical Society (ACS), 1993. |
| سنة النشر: | 1993 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Hydrolysis, Ammonium hydroxide, chemistry, Ammonium nitrate, Oxidizing agent, Environmental Chemistry, Organic chemistry, Alcohol, General Chemistry, Hexadecane, Cetane number, Nitric oxide |
| الوصف: | The selective removal of nitric oxide from gas streams was investigated using 3,6-dimethyl-3-octyl hydroperoxide, p-menthanyl hydroperoxide, pinanyl hydroperoxide, and cumenyl hydroperoxide in solutions of n-hexadecane (cetane). The influence of different variables such as temperature, gas stream flow rate (or residence time), and concentration of hydroperoxide compounds on rate of NO removal was evaluated. The NO reacted with the hydroperoxides to produce allyl nitrates. These are easily hydrolyzed with ammonium hydroxide to ammonium nitrate and the alcohol |
| تدمد: | 1520-5851 0013-936X |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::8c95f8e090d5625efc69b14765edc712 https://doi.org/10.1021/es00038a013 |
| رقم الأكسشن: | edsair.doi...........8c95f8e090d5625efc69b14765edc712 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205851 0013936X |
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