Nucleophilic substitution in the 10,11-dihydrodibenz[b,f]iodepinium cation
| العنوان: | Nucleophilic substitution in the 10,11-dihydrodibenz[b,f]iodepinium cation |
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| المؤلفون: | Nikolay A. Bumagin, A. N. Vanchikov, T. P. Tolstaya, L. I. Sukhomlinova |
| المصدر: | Chemistry of Heterocyclic Compounds. 35:106-111 |
| بيانات النشر: | Springer Science and Business Media LLC, 1999. |
| سنة النشر: | 1999 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Aqueous solution, Tetrafluoroborate, chemistry, Organic Chemistry, Nucleophilic substitution, Phenanthrene, Medicinal chemistry, Ion |
| الوصف: | 10,11-Dihydrodibenz[b,f]iodepinium tetrafluoroborate gave only 1-(2-azidophenyl)-2-(2-iodophenylethane with the N3− in aqueous DMSO, while with NO2− it gave 1-(2-nitrophenyl)-2-(2-iodophenyl)ethane (93%), 9,10-dihydrophenanthrene (5%), and traces of phenanthrene. Both in pure and aqueous DMSO this cation with the Br− ion was converted into phenanthrene (80% and 68% respectively) and 1-(2-bromophenyl)-2-(2-iodophenyl)ethane (10 and 20%), while in water it gave 9,10-dihydrophenanthrene (75%) and phenanthrene (5%). A new route for the synthesis of 1-(2-aminophenyl)-2-phenylethane starting from this tetrafluoroborate has been proposed. |
| تدمد: | 1573-8353 0009-3122 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::8de01f7bbf25e63134b70a715d765ab7 https://doi.org/10.1007/bf02251673 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........8de01f7bbf25e63134b70a715d765ab7 |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 15738353 00093122 |
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