Hierarchically 1D CdS decorated on 2D perovskite-type La2Ti2O7 nanosheet hybrids with enhanced photocatalytic performance
العنوان: | Hierarchically 1D CdS decorated on 2D perovskite-type La2Ti2O7 nanosheet hybrids with enhanced photocatalytic performance |
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المؤلفون: | Liang Mao, Xiao-Yan Cai, Mingshan Zhu |
المصدر: | Rare Metals. 40:1067-1076 |
بيانات النشر: | Springer Science and Business Media LLC, 2020. |
سنة النشر: | 2020 |
مصطلحات موضوعية: | Materials science, 020502 materials, Metals and Alloys, Environmental pollution, Heterojunction, 02 engineering and technology, Condensed Matter Physics, Cadmium sulfide, chemistry.chemical_compound, 0205 materials engineering, X-ray photoelectron spectroscopy, chemistry, Chemical engineering, Materials Chemistry, Rhodamine B, Photocatalysis, Water splitting, Physical and Theoretical Chemistry, Nanosheet |
الوصف: | In this paper, a heterojunction of hierarchically one-dimensional (1D) cadmium sulfide (CdS) nanowires decorated on the two-dimensional (2D) La2Ti2O7 (LTO) has been fabricated by a simple two-step hydrothermal process. The structure, morphology and surface chemical composition of CdS/LTO were studied by a variety of characterizations, in which the X-ray photoelectron spectroscopy (XPS) results showed a strong interaction between CdS and LTO through S–O bonds. The type II band alignment of CdS/LTO for favorable electron transfer from CdS to LTO and hole transfer from LTO to CdS was clarified by ultraviolet–visible (UV–Vis) diffuse reflectance spectroscopy and Mott–Schottky (M–S) plot measurements. In the absence of any co-catalyst, H2 production from water splitting and Rhodamine B (RhB) decomposition in aqueous solution were carried out to evaluate the photocatalytic activities, showing that the photocatalytic performance of CdS/LTO was superior to that of pure LTO and CdS under visible light and simulated sunlight. The optimal CdS content in the CdS/LTO system was determined to be 7.5 wt%. The present results show an effective pathway to design a 1D/2D heterojunction photocatalyst in the face of overwhelming problems of energy crisis and environmental pollution. |
تدمد: | 1867-7185 1001-0521 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::8f0606fee984c4fb0adea7da2283146b https://doi.org/10.1007/s12598-020-01589-w |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........8f0606fee984c4fb0adea7da2283146b |
قاعدة البيانات: | OpenAIRE |
تدمد: | 18677185 10010521 |
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