Synthesis and Electronic Transitions of the Dye Based on 1-{2-[4-(3-Hydroxy-2-oxo-2H-chromen-4-yl)phenyl]-2-oxoethyl}-4-methylpyridinium Bromide
العنوان: | Synthesis and Electronic Transitions of the Dye Based on 1-{2-[4-(3-Hydroxy-2-oxo-2H-chromen-4-yl)phenyl]-2-oxoethyl}-4-methylpyridinium Bromide |
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المؤلفون: | O. V. Skrypska, D. O. Melnyk, Roman Lytvyn, Kh. Ye. Pitkovych, Mykola D. Obushak, O. V. Rusnak, P. I. Yagodinets |
المصدر: | Russian Journal of General Chemistry. 90:602-609 |
بيانات النشر: | Pleiades Publishing Ltd, 2020. |
سنة النشر: | 2020 |
مصطلحات موضوعية: | 010405 organic chemistry, General Chemistry, Chromophore, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, 0104 chemical sciences, Benzaldehyde, chemistry.chemical_compound, chemistry, Atomic electron transition, Bromide, Pyridine, Pyridinium, Methylpyridinium, Absorption (chemistry) |
الوصف: | 4-[4-(2-Bromoacetyl)phenyl]-3-hydroxy-2H-chromen-2-one reacted with pyridine and 4-methylpyridine to give the corresponding quaternary pyridinium salts. The condensation of 1-{2-[4-(3-hydroxy-2-oxo-2H-chromen-4-yl)phenyl]-2-oxoethyl}-4-methylpyridinium bromide with 4-(dimethylamino)benzaldehyde afforded a new biscyanine dye whose electronic spectrum showed two absorption maxima originating from interactions of chromophores. The nature of electronic transitions in the dye molecule was analyzed by quantum chemical calculations. |
تدمد: | 1608-3350 1070-3632 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::974653f1dcdf7da6ecc03ca30ddd4fa5 https://doi.org/10.1134/s1070363220040076 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........974653f1dcdf7da6ecc03ca30ddd4fa5 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 16083350 10703632 |
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