The effect of detonation decoupling on the ignition capability of a pulse detonation igniter in a scramjet cavity is investigated. It was observed that a strongly coupled detonation is required for igniting a fueled cavity and the ignition capability rapidly decays for a weak or slightly decoupled detonation. The pulse detonation igniter pressure and wave speed were measured at subatmospheric pressure to characterize the pressure and fill characteristics dependence on backpressure. Temperatures measurements using 100 kHz H2O absorption measurements showed an increase in peak temperature for critically filled conditions but a decrease in bulk fluid temperature with decreasing fill time. Simultaneous schlieren and chemiluminescence measurements demonstrate that a fully coupled detonation entrains greater quantities of high-temperature and reacting fluid in the vortex formed on the edges of the detonation plume, enhancing the mixing and spreading of products into the cavity. This shedding of high-temperature intermediate species is the primary mechanism governing successful ignition in the scramjet cavity.