Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols
العنوان: | Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols |
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المؤلفون: | Benjamin List, Jung Tae Han, Hui Zhou |
المصدر: | Synlett. |
بيانات النشر: | Georg Thieme Verlag KG, 2023. |
سنة النشر: | 2023 |
مصطلحات موضوعية: | Organic Chemistry |
الوصف: | We report a Brønsted acid catalyzed enantioselective silylation of biaryl diols with an allylsilane as silicon source. This process enables facile access to enantioenriched biaryl silyl ethers with an axial stereogenicity. A control experiment supports a mechanism proceeding by desymmetrization followed by kinetic resolution. |
تدمد: | 1437-2096 0936-5214 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::9ee8cbca9a6ab9cfee82c3cc46412b55 https://doi.org/10.1055/a-2100-1575 |
حقوق: | OPEN |
رقم الأكسشن: | edsair.doi...........9ee8cbca9a6ab9cfee82c3cc46412b55 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 14372096 09365214 |
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