Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols
| العنوان: | Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols |
|---|---|
| المؤلفون: | Benjamin List, Jung Tae Han, Hui Zhou |
| المصدر: | Synlett. |
| بيانات النشر: | Georg Thieme Verlag KG, 2023. |
| سنة النشر: | 2023 |
| مصطلحات موضوعية: | Organic Chemistry |
| الوصف: | We report a Brønsted acid catalyzed enantioselective silylation of biaryl diols with an allylsilane as silicon source. This process enables facile access to enantioenriched biaryl silyl ethers with an axial stereogenicity. A control experiment supports a mechanism proceeding by desymmetrization followed by kinetic resolution. |
| تدمد: | 1437-2096 0936-5214 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::9ee8cbca9a6ab9cfee82c3cc46412b55 https://doi.org/10.1055/a-2100-1575 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi...........9ee8cbca9a6ab9cfee82c3cc46412b55 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14372096 09365214 |
|---|