17O NMR Studies of Titanate Repolymerization in Water
| العنوان: | 17O NMR Studies of Titanate Repolymerization in Water |
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| المؤلفون: | B. C. Bunker, Charles H. F. Peden, R. J. Kirkpatrick, G. L. Turner |
| المصدر: | MRS Proceedings. 432 |
| بيانات النشر: | Springer Science and Business Media LLC, 1996. |
| سنة النشر: | 1996 |
| مصطلحات موضوعية: | NMR spectra database, Materials science, chemistry, Ion exchange, Inorganic chemistry, Physical chemistry, chemistry.chemical_element, Molecule, Protonation, Spectroscopy, Condensation reaction, Titanate, Titanium |
| الوصف: | Local structures of high surface area sodium titanate materials have been examined as a function of pH using solid state 17O nuclear magnetic resonance (NMR) spectroscopy. Using 17O NMR, it is possible to determine the relative populations of nonbridging oxygens as well as oxygens bridging between two, three, and four titanium atoms. Results show that protonation of ion exchange sites in titanate materials is not a simple ion exchange process but involves a repolymerization and restructuring of the titanate network. The observed structural changes are consistent with reported phase stabilities of titanates in water as well as with known hydrolysis and condensation reactions. |
| تدمد: | 1946-4274 0272-9172 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::a1b7e4fdcfdfb11acd76689b23441993 https://doi.org/10.1557/proc-432-39 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........a1b7e4fdcfdfb11acd76689b23441993 |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 19464274 02729172 |
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