Optical Absorption Characteristics For 7F0'→5L6' and 7F0'→ 7F6' Transitions of Trivalent Americium Ion in Aqueous Electrolyte Mixtures
| العنوان: | Optical Absorption Characteristics For 7F0'→5L6' and 7F0'→ 7F6' Transitions of Trivalent Americium Ion in Aqueous Electrolyte Mixtures |
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| المؤلفون: | Colt R. Heathman, Travis S. Grimes, Peter R. Zalupski, Dean R. Peterman |
| المصدر: | Applied Spectroscopy. 71:2608-2615 |
| بيانات النشر: | SAGE Publications, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Aqueous solution, 010405 organic chemistry, Inorganic chemistry, chemistry.chemical_element, Americium, Electrolyte, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Ion, Absorbance, chemistry.chemical_compound, Solvation shell, Nitrate, chemistry, Physical chemistry, sense organs, Spectroscopy, Instrumentation |
| الوصف: | Optical absorption features for [Formula: see text] and [Formula: see text] transitions of trivalent americium ion were investigated in a wide range of aqueous combinations of perchloric and nitric acids (0.1–6.0 mol L−1). The developed qualitative matrix of extinction coefficients measures the cumulative impact of increasing electrolyte content, changes in the hydration zones of americium ion, and inner-sphere perturbation by nitrate on the absorbance. The effects of growing complexity of aqueous electrolyte medium were highlighted for the [Formula: see text] transition. Spectroscopy indicates the perturbation of the inner hydration sphere of trivalent f-element by one nitrate ligand. |
| تدمد: | 1943-3530 0003-7028 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::a924c20fb884ef24d7ea69763376fdb9 https://doi.org/10.1177/0003702817721528 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi...........a924c20fb884ef24d7ea69763376fdb9 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 19433530 00037028 |
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