Copolymerization of 2-Ethylhexyl Acrylate and D-Limonene
العنوان: | Copolymerization of 2-Ethylhexyl Acrylate and D-Limonene |
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المؤلفون: | Marc A. Dubé, Yujie Zhang |
المصدر: | Polymer-Plastics Technology and Engineering. 54:499-505 |
بيانات النشر: | Informa UK Limited, 2014. |
سنة النشر: | 2014 |
مصطلحات موضوعية: | Acrylate, D limonene, Materials science, Polymers and Plastics, General Chemical Engineering, Materials Science (miscellaneous), Chain transfer, Benzoyl peroxide, chemistry.chemical_compound, Polymerization, chemistry, Polymer chemistry, Materials Chemistry, medicine, Copolymer, Reactivity (chemistry), 2-ethylhexyl acrylate, medicine.drug |
الوصف: | The bulk free radical copolymerization of D-limonene and 2-ethylhexyl acrylate (EHA) was conducted at 80°C using benzoyl peroxide (BPO) as initiator. Low conversion experiments were conducted to estimate the copolymer reactivity ratios. The reactivity ratios r1 = 6.896 and r2 = 0.032 (1 = EHA, 2 = d-limonene) were obtained using a non-linear, error-in-variables method with the RREVM computer program. High conversion experiments were performed and revealed that a degradative chain transfer mechanism for D-limonene dominated the polymerization. |
تدمد: | 1525-6111 0360-2559 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::abc79712ee2c0736dffa26cfbed0905f https://doi.org/10.1080/03602559.2014.961080 |
رقم الأكسشن: | edsair.doi...........abc79712ee2c0736dffa26cfbed0905f |
قاعدة البيانات: | OpenAIRE |
تدمد: | 15256111 03602559 |
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