التفاصيل البيبلوغرافية
| العنوان: |
MARKOVNIKOV VINYLBORINATES FROM 9-OXA-10-BORABICYCLO[3.3.2]DECANES |
| المؤلفون: |
Karl Matos, John A. Soderquist, Jorge Ramos |
| المصدر: |
Tetrahedron Letters. 38:6639-6642 |
| بيانات النشر: |
Elsevier BV, 1997. |
| سنة النشر: |
1997 |
| مصطلحات موضوعية: |
Coupling (electronics), chemistry.chemical_classification, Group (periodic table), Chemistry, Organic Chemistry, Drug Discovery, Markovnikov's rule, Biochemistry, Medicinal chemistry, Alkyl |
| الوصف: |
Alkylborinates 1 react with α-methoxyvinyllithium (LiAMV) to produce stable “ate” complexes, 2 , which undergo BCl 3 -induced alkyl group migration providing new air-stable vinylborinates, 3 . These intermediates which are readily converted to either unsymmetrical 1,1-disubstituted alkenes ( 7 ) via the Suzuki-Miyaura coupling or, oxidatively, to methyl ketones, ( 8 ), one of which was converted to the antihistaminic drug, metron S, 10 . © 1997 Elsevier Science Ltd. |
| تدمد: |
0040-4039 |
| URL الوصول: |
https://explore.openaire.eu/search/publication?articleId=doi_________::b43ba3bffd59c503e35f360a84a2dcbe
https://doi.org/10.1016/s0040-4039(97)01578-5 |
| حقوق: |
CLOSED |
| رقم الأكسشن: |
edsair.doi...........b43ba3bffd59c503e35f360a84a2dcbe |
| قاعدة البيانات: |
OpenAIRE |
