New organic extractant based on pyridazinone scaffold compounds: Liquid-liquid extraction study and DFT calculations

التفاصيل البيبلوغرافية
العنوان: New organic extractant based on pyridazinone scaffold compounds: Liquid-liquid extraction study and DFT calculations
المؤلفون: Brahim Hacht, Faisal A. Almalki, Noureddine Benchat, Tarik Chelfi, Abdelmalek Elaatiaoui, Fouad El Kalai, Mohamed Bouklah, Taibi Ben Hadda, Said Daoui, Mustapha Allali
المصدر: Journal of Molecular Structure. 1191:24-31
بيانات النشر: Elsevier BV, 2019.
سنة النشر: 2019
مصطلحات موضوعية: Aqueous solution, 010405 organic chemistry, Ligand, Metal ions in aqueous solution, Organic Chemistry, Inorganic chemistry, Extraction (chemistry), chemistry.chemical_element, Zinc, 010402 general chemistry, 01 natural sciences, Copper, 0104 chemical sciences, Analytical Chemistry, Inorganic Chemistry, chemistry, Transition metal, Liquid–liquid extraction, Spectroscopy
الوصف: In this work, the synthesis of new organic compounds is reported based on pyridazin-3-(2H)-one compounds. The extraction efficiency of metal ions (e.g. Lead Pb(II), Cadmium Cd(II), Copper Cu(II) and Zinc Zn(II)) from aqueous solutions to organic solutions of those compounds was studied. Accordingly, the studied ligands show a remarkable affinity for the transition metals, especially Zn(II) with (Ligand L5), Cu(II) and Cd(II) with (Ligand L3) in the presence of withdrawing and donor electron group. Theoretical calculations DFT were made in order to get better insight into the geometry of the studied ligands.
تدمد: 0022-2860
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::b66ef0ff39dfd0dbb222c378222a5aff
https://doi.org/10.1016/j.molstruc.2019.04.033
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........b66ef0ff39dfd0dbb222c378222a5aff
قاعدة البيانات: OpenAIRE