Preparation of Alkyl and Aryl Chlorodifluoromethyl Ethers Using BrF3
| العنوان: | Preparation of Alkyl and Aryl Chlorodifluoromethyl Ethers Using BrF3 |
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| المؤلفون: | Michael J. Welch, Revital Sasson, Youlia Hagooly, Shlomo Rozen |
| المصدر: | European Journal of Organic Chemistry. 2008:2875-2880 |
| بيانات النشر: | Wiley, 2008. |
| سنة النشر: | 2008 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Thiophosgene, Bromine trifluoride, chemistry.chemical_compound, chemistry, Aryl, Organic Chemistry, Organic chemistry, Physical and Theoretical Chemistry, Alkyl |
| الوصف: | Both alkyl and aryl chlorothioformates could readily be obtained from the corresponding alcohols and thiophosgene. These families of compounds were treated with BrF3 to form the corresponding alkyl and aryl chlorodifluoromethyl ethers in 60–85 % yields. The method is suitable for constructing a variety of aliphatic as well as electron-deficient aromatic chlorodifluoromethyl ethers. The reactions proceed under mild conditions and short reaction times. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) |
| تدمد: | 1099-0690 1434-193X |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::b7fb7cc52f91fcd153c3c7b1ae06d307 https://doi.org/10.1002/ejoc.200800231 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........b7fb7cc52f91fcd153c3c7b1ae06d307 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10990690 1434193X |
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