Pentafluorosulfanyl group: an emerging tool in optoelectronic materials

التفاصيل البيبلوغرافية
العنوان: Pentafluorosulfanyl group: an emerging tool in optoelectronic materials
المؤلفون: Julian M. W. Chan
المصدر: Journal of Materials Chemistry C. 7:12822-12834
بيانات النشر: Royal Society of Chemistry (RSC), 2019.
سنة النشر: 2019
مصطلحات موضوعية: Materials science, Group (periodic table), Optoelectronic materials, Materials Chemistry, Nanotechnology, 02 engineering and technology, General Chemistry, Materials design, 010402 general chemistry, 021001 nanoscience & nanotechnology, 0210 nano-technology, 01 natural sciences, 0104 chemical sciences
الوصف: The pentafluorosulfanyl (SF5) moiety is a lesser known and underutilized functional group that displays high electronegativity, chemical and thermal stability, and low surface energy, among other useful properties. Despite being around for almost 60 years, practical application of the unique SF5 group in various areas of chemistry has only recently picked up, which is mostly due to longstanding challenges associated with its synthetic accessibility. While most of the latest attention involving the use of SF5 has been in medicinal chemistry, it has also started to feature much more frequently in functional materials design, especially in the area of optoelectronic materials. This review will describe the ways in which the distinctive properties of SF5 have been harnessed to tune the optoelectronic character of different classes of functional materials, starting with the earliest examples from the late 1990s to the intensive research efforts in recent years.
تدمد: 2050-7534
2050-7526
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::b9c390633afea80a633c4a267bf79d3c
https://doi.org/10.1039/c9tc01949a
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........b9c390633afea80a633c4a267bf79d3c
قاعدة البيانات: OpenAIRE