High-temperature solution polymerization of butyl acrylate/methyl methacrylate: Reactivity ratio estimation
| العنوان: | High-temperature solution polymerization of butyl acrylate/methyl methacrylate: Reactivity ratio estimation |
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| المؤلفون: | Marc A. Dubé, V. Verhoeven, Neil T. McManus, Alexander Penlidis, Malik Hakim |
| المصدر: | Journal of Applied Polymer Science. 77:602-609 |
| بيانات النشر: | Wiley, 2000. |
| سنة النشر: | 2000 |
| مصطلحات موضوعية: | Polymers and Plastics, Kinetic model, Butyl acrylate, Analytical chemistry, Solution polymerization, General Chemistry, Atmospheric temperature range, Toluene, Surfaces, Coatings and Films, chemistry.chemical_compound, chemistry, Polymer chemistry, Materials Chemistry, Copolymer, Reactivity (chemistry), Methyl methacrylate |
| الوصف: | Solution copolymerizations of butyl acrylate/methyl methacrylate in toluene were performed over an expanded temperature range (60–140°C) compared to more typical ranges that do not exceed 80°C. From a large amount of data collected independently at two laboratories, reactivity ratios were estimated at five different temperatures. The reactivity ratios were estimated from low conversion copolymer composition data using both the error-in-variables model method and a nonlinear parameter estimation based on the integrated copolymer composition equation. Using all of the available data, temperature-dependent expressions were developed for the reactivity ratios and compared to previously published bulk copolymerization values. No significant differences appeared to exist between the bulk and solution polymerization reactivity ratios. Furthermore, the copolymer composition data conformed to the Mayo-Lewis kinetic model over the entire temperature range. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 602–609, 2000 |
| تدمد: | 1097-4628 0021-8995 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::be9802230b9168f3ab02c7abda9b62ae https://doi.org/10.1002/(sici)1097-4628(20000718)77:3<602::aid-app15>3.0.co;2-f |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........be9802230b9168f3ab02c7abda9b62ae |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10974628 00218995 |
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