ChemInform Abstract: Stereoselective Total Synthesis of (.+-.)-Homochelidonine
| العنوان: | ChemInform Abstract: Stereoselective Total Synthesis of (.+-.)-Homochelidonine |
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| المؤلفون: | Makoto Yoshida, Toshiko Watanabe, Tsutomu Ishikawa |
| المصدر: | ChemInform. 33 |
| بيانات النشر: | Wiley, 2010. |
| سنة النشر: | 2010 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Chelerythrine, chemistry, Phenanthridine, Stereochemistry, Alkaloid, Tetralone, Arnottin II, Total synthesis, Stereoselectivity, General Medicine, Homochelidonine |
| الوصف: | (±)-Homochelidonine, a B/C- cis -11-hydroxyhexahydrobenzo[ c ]phenanthridine alkaloid, was stereoselectively synthesized from arnottin II, a non-alkaloidal spirolactonyl tetralone which had been structurally correlated to chelerythrine, a fully aromatized-type alkaloid, by the common use of a 2-benzofuranyl-1-tetralone as a synthetic key intermediate. Thus, a valuable synthetic method accessible to benzo[ c ]phenanthridine alkaloids with different oxidation stages of the basic skeleton could be proposed. |
| تدمد: | 1522-2667 0931-7597 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::d3a5b1b2dcd86ab629440b6d4f5a3de1 https://doi.org/10.1002/chin.200250188 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........d3a5b1b2dcd86ab629440b6d4f5a3de1 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15222667 09317597 |
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