Excess Molar Enthalpies of Binary Mixtures Containing 1-Methyl-3-octyl-imidazolium Tetrafluoroborate and Alcohols at T = 298.15 K
| العنوان: | Excess Molar Enthalpies of Binary Mixtures Containing 1-Methyl-3-octyl-imidazolium Tetrafluoroborate and Alcohols at T = 298.15 K |
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| المؤلفون: | Handi Yin, Zhencun Cui, Dashuang Fan, Weiguo Shen, Dongxing Cai |
| المصدر: | Journal of Chemical & Engineering Data. 59:678-683 |
| بيانات النشر: | American Chemical Society (ACS), 2014. |
| سنة النشر: | 2014 |
| مصطلحات موضوعية: | Molar, UNIQUAC, Ethanol, Tetrafluoroborate, General Chemical Engineering, Alcohol, General Chemistry, Isothermal process, Calorimeter, chemistry.chemical_compound, chemistry, Organic chemistry, Physical chemistry, Titration |
| الوصف: | An isothermal titration calorimeter was used to measure the excess molar enthalpies (HE) at T = 298.15 K for five binary systems: 1-methyl-3-octyl-imidazolium tetrafluoroborate (OmimBF4) + alcohols (ethanol, 1-propanol, 2-propanol, 1-butanol, and 1-pentanol). The values of HE were found to be all positive for the five systems and were fitted with the Redlich–Kister polynomial and the UNIQUAC mode. The magnitude order of HE for the five systems was explained by the balance between the magnitude orders of enthalpies of the alcohol/alcohol and the alcohol/OmimBF4 interactions. |
| تدمد: | 1520-5134 0021-9568 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::db1619317d0f5d3dc2a6b5a97e86d253 https://doi.org/10.1021/je400709f |
| رقم الأكسشن: | edsair.doi...........db1619317d0f5d3dc2a6b5a97e86d253 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15205134 00219568 |
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