Novel polyurethane networks based on hybrid inorganic/organic phosphazene-containing nanotubes with surface active hydroxyl groups

التفاصيل البيبلوغرافية
العنوان: Novel polyurethane networks based on hybrid inorganic/organic phosphazene-containing nanotubes with surface active hydroxyl groups
المؤلفون: Jiawei Zhang, Li Liu, Jing Li, Wei Liu, Yuanli Zheng, Xiaozhen Tang, Xiaobin Huang, Xiaoqi Kang
المصدر: Polymers for Advanced Technologies. 23:1-7
بيانات النشر: Wiley, 2010.
سنة النشر: 2010
مصطلحات موضوعية: Thermogravimetric analysis, chemistry.chemical_compound, Materials science, Nanocomposite, Polymers and Plastics, Biocompatibility, chemistry, Pulmonary surfactant, Ultimate tensile strength, Thermal stability, Composite material, Phosphazene, Polyurethane
الوصف: Recently, our group reported a novel preparation of poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) nanotubes (PZSNTs), which could be conveniently prepared in a one-pot process at room temperature without any surfactant or other compatibilizing agent. PZSNTs were a new kind of phosphazene-containing crosslinked polymers which attracted considerable interest for their outstanding biocompatibility, thermal stability, and flame-retardant property. Moreover, PZSNTs which possessed inherent surface active hydroxyl groups could be directly used as a crosslinking agent to prepare polyurethane hybrid networks. PZSNTs were homogeneously dispersed in the polyurethane matrix. Tensile tests indicated that the nanocomposites were significantly reinforced by crosslinking of PZSNTs. The tensile strength was enhanced from 11.4 to 21.5 MPa while the elongation at break was almost invariable (460–430%). The storage moduli of the nanocomposites were significantly higher than that of the pure polyurethane. In terms of thermogravimetric analysis (TGA), the nanocomposites displayed an improved thermal stability. Copyright © 2010 John Wiley & Sons, Ltd.
تدمد: 1042-7147
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::db93d1cc4bcde5d6cbd715d5ea7616f6
https://doi.org/10.1002/pat.1817
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........db93d1cc4bcde5d6cbd715d5ea7616f6
قاعدة البيانات: OpenAIRE