Synthesis and Characterization of Novel Tetrapyrazinoporphyrazine Derivatives Containing Morpholine andtert-Butyl Group

التفاصيل البيبلوغرافية
العنوان: Synthesis and Characterization of Novel Tetrapyrazinoporphyrazine Derivatives Containing Morpholine andtert-Butyl Group
المؤلفون: Song Hak Kim, Seung Hwan Byun, Chun Keun Jang, Jae Yun Jaung, Do Kyung Lee
المصدر: Molecular Crystals and Liquid Crystals. 509:96/[838]-107/[849]
بيانات النشر: Informa UK Limited, 2009.
سنة النشر: 2009
مصطلحات موضوعية: Tert butyl, Pyrazine, Chemistry, Magnesium, chemistry.chemical_element, General Chemistry, Condensed Matter Physics, Copper, Catalysis, chemistry.chemical_compound, Elemental analysis, Morpholine, Cuprous chloride, Organic chemistry, General Materials Science, Nuclear chemistry
الوصف: Tetrapyrazinoporphyrazine magnesium complexes were synthesized from 2,3-dicyano-5-(4-alkylphenyl)-6-(4-morpholinophenyl)pyrazine derivatives using freshly prepared solutions of magnesium butoxide in n-butanol. The corresponding metal-free derivatives were obtained by treatment with p-toluenesulfonic acid. Copper complexes were successfully synthesized using excess cuprous chloride and DBU (1,8-diazabicyclo[5,4,0]-7-undecene) as a catalyst in o-dichlorobenzene under reflux. The tetrapyrazinoporphyrazines were characterized by elemental analysis, UV-visible spectra, IR, MALDI-TOF Ms and 1H-NMR spectra.
تدمد: 1563-5287
1542-1406
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::de957cbcc6426cf334fa4cf95e10fa77
https://doi.org/10.1080/15421400903054121
رقم الأكسشن: edsair.doi...........de957cbcc6426cf334fa4cf95e10fa77
قاعدة البيانات: OpenAIRE