Synthesis and Characterization of Novel Tetrapyrazinoporphyrazine Derivatives Containing Morpholine andtert-Butyl Group
العنوان: | Synthesis and Characterization of Novel Tetrapyrazinoporphyrazine Derivatives Containing Morpholine andtert-Butyl Group |
---|---|
المؤلفون: | Song Hak Kim, Seung Hwan Byun, Chun Keun Jang, Jae Yun Jaung, Do Kyung Lee |
المصدر: | Molecular Crystals and Liquid Crystals. 509:96/[838]-107/[849] |
بيانات النشر: | Informa UK Limited, 2009. |
سنة النشر: | 2009 |
مصطلحات موضوعية: | Tert butyl, Pyrazine, Chemistry, Magnesium, chemistry.chemical_element, General Chemistry, Condensed Matter Physics, Copper, Catalysis, chemistry.chemical_compound, Elemental analysis, Morpholine, Cuprous chloride, Organic chemistry, General Materials Science, Nuclear chemistry |
الوصف: | Tetrapyrazinoporphyrazine magnesium complexes were synthesized from 2,3-dicyano-5-(4-alkylphenyl)-6-(4-morpholinophenyl)pyrazine derivatives using freshly prepared solutions of magnesium butoxide in n-butanol. The corresponding metal-free derivatives were obtained by treatment with p-toluenesulfonic acid. Copper complexes were successfully synthesized using excess cuprous chloride and DBU (1,8-diazabicyclo[5,4,0]-7-undecene) as a catalyst in o-dichlorobenzene under reflux. The tetrapyrazinoporphyrazines were characterized by elemental analysis, UV-visible spectra, IR, MALDI-TOF Ms and 1H-NMR spectra. |
تدمد: | 1563-5287 1542-1406 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::de957cbcc6426cf334fa4cf95e10fa77 https://doi.org/10.1080/15421400903054121 |
رقم الأكسشن: | edsair.doi...........de957cbcc6426cf334fa4cf95e10fa77 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 15635287 15421406 |
---|