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Separation of 2-Pentanol Racemate on a Chiral Stationary Phase Based on Homochiral NiSO4·6H2O Crystals Obtained under Viedma Ripening

التفاصيل البيبلوغرافية
العنوان: Separation of 2-Pentanol Racemate on a Chiral Stationary Phase Based on Homochiral NiSO4·6H2O Crystals Obtained under Viedma Ripening
المؤلفون: V. Yu. Gus’kov, Yu. F. Sharafutdinova, A. Sh. Ganieva
المصدر: Journal of Analytical Chemistry. 76:1093-1097
بيانات النشر: Pleiades Publishing Ltd, 2021.
سنة النشر: 2021
مصطلحات موضوعية: Range (particle radiation), chemistry.chemical_compound, Chloroform, Column chromatography, chemistry, Separation (statistics), Volume fraction, Analytical chemistry, 2-Pentanol, Ripening, Selectivity, Analytical Chemistry
الوصف: A new chiral stationary phase based on homochiral crystals of α-NiSO4∙6H2O obtained under the condition of Viedma ripening is proposed for the separation of 2-pentanol racemate. The retention times and separation parameters are determined from chromatograms of the separation of 2-pentanol racemate. Separation occurs in the concentration range 4–11.3 mg/mL (eluent is a mixture of n-heptane and chloroform). The reliability of the separation is confirmed by polarimetry and the gas-chromatographic analysis of the fractions of each peak with mass-spectrometric detection. It is shown that the separation parameters do not depend on the elution rate. With an increase in the volume fraction of chloroform, the eluting force increases, and the separation criterion and the selectivity coefficient decrease. The latter range from 1.09 to 1.32. The maximum separation efficiency was 2000 tp/m. The proposed stationary phase can be used for the semi-preparative separation of ennatiomers.
تدمد: 1608-3199
1061-9348
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::e5594e67caa10e535afb12bdac675210
https://doi.org/10.1134/s1061934821090100
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........e5594e67caa10e535afb12bdac675210
قاعدة البيانات: OpenAIRE
الوصف
تدمد:16083199
10619348