Application of trityl moieties in chemical processes: part I
العنوان: | Application of trityl moieties in chemical processes: part I |
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المؤلفون: | Saeed Baghery, Mohammad Ali Zolfigol, Vajiheh Behranvand, Mahmoud Zarei, Shadpour Mallakpour |
المصدر: | Journal of the Iranian Chemical Society. 17:2737-2843 |
بيانات النشر: | Springer Science and Business Media LLC, 2020. |
سنة النشر: | 2020 |
مصطلحات موضوعية: | 010405 organic chemistry, Carbohydrate chemistry, Chemistry, Hydride, General Chemistry, 010402 general chemistry, 01 natural sciences, Combinatorial chemistry, Chemical reaction, Redox, 0104 chemical sciences, Catalysis, chemistry.chemical_compound, Reagent, Peptide synthesis, Lewis acids and bases |
الوصف: | Triphenylcarbenium ions (trityl cations: [RPh]3C+) are broadly identified organic compounds, because of their several uses, such as protective group, a catalyst for C–C bond formation, dye chemistry, carbohydrate chemistry, oxidation and reduction reagent, polymer and peptide synthesis, chiral catalyst, activity-based probes, and photochemical reactions. Trityl cations have also been applied as neutral Lewis acids in different chemical reactions. Possibly, the trityl cation is most widely used in hydride abstraction reactions both in the study of mechanisms transformations (organometallic and organic) and in organic syntheses. Ph3C+ is also extensively applied as very efficient activators and as one-electron oxidants for olefin polymerization reactions. In this review, we explain applications of trityl moieties in chemical processes and synthesis. |
تدمد: | 1735-2428 1735-207X |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::e7374086a3e6c01b67f196d8128f01d7 https://doi.org/10.1007/s13738-020-01980-5 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........e7374086a3e6c01b67f196d8128f01d7 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 17352428 1735207X |
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