Application of trityl moieties in chemical processes: part I

التفاصيل البيبلوغرافية
العنوان: Application of trityl moieties in chemical processes: part I
المؤلفون: Saeed Baghery, Mohammad Ali Zolfigol, Vajiheh Behranvand, Mahmoud Zarei, Shadpour Mallakpour
المصدر: Journal of the Iranian Chemical Society. 17:2737-2843
بيانات النشر: Springer Science and Business Media LLC, 2020.
سنة النشر: 2020
مصطلحات موضوعية: 010405 organic chemistry, Carbohydrate chemistry, Chemistry, Hydride, General Chemistry, 010402 general chemistry, 01 natural sciences, Combinatorial chemistry, Chemical reaction, Redox, 0104 chemical sciences, Catalysis, chemistry.chemical_compound, Reagent, Peptide synthesis, Lewis acids and bases
الوصف: Triphenylcarbenium ions (trityl cations: [RPh]3C+) are broadly identified organic compounds, because of their several uses, such as protective group, a catalyst for C–C bond formation, dye chemistry, carbohydrate chemistry, oxidation and reduction reagent, polymer and peptide synthesis, chiral catalyst, activity-based probes, and photochemical reactions. Trityl cations have also been applied as neutral Lewis acids in different chemical reactions. Possibly, the trityl cation is most widely used in hydride abstraction reactions both in the study of mechanisms transformations (organometallic and organic) and in organic syntheses. Ph3C+ is also extensively applied as very efficient activators and as one-electron oxidants for olefin polymerization reactions. In this review, we explain applications of trityl moieties in chemical processes and synthesis.
تدمد: 1735-2428
1735-207X
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::e7374086a3e6c01b67f196d8128f01d7
https://doi.org/10.1007/s13738-020-01980-5
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........e7374086a3e6c01b67f196d8128f01d7
قاعدة البيانات: OpenAIRE