Systematic study of the chemical and hydrothermal stability of selected 'stable' Metal Organic Frameworks

التفاصيل البيبلوغرافية
العنوان: Systematic study of the chemical and hydrothermal stability of selected 'stable' Metal Organic Frameworks
المؤلفون: Henk Vrielinck, Hannes Depauw, Thomas Bogaerts, Pascal Van Der Voort, Veronique Van Speybroeck, Karen Leus, Jeroen De Decker, Kevin Hendrickx
المصدر: Microporous and Mesoporous Materials. 226:110-116
بيانات النشر: Elsevier BV, 2016.
سنة النشر: 2016
مصطلحات موضوعية: Chemistry, Inorganic chemistry, 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, Hydrothermal circulation, 0104 chemical sciences, Crystallinity, Mechanics of Materials, General Materials Science, Chemical stability, Metal-organic framework, Acid–base reaction, 0210 nano-technology, Porosity, Zeolitic imidazolate framework
الوصف: In this work, the hydrothermal and chemical stability towards acids, bases, air, water, and peroxides of Metal Organic Frameworks, that are commonly considered to be stable, is presented. As a proof of stability both the crystallinity and porosity are measured before and after exposure to the stress test. The major part of the MOFs examined in this study show a good hydrothermal stability except for UiO-67, NH 2 -MIL-101 (Al) and CuBTC. The chemical stabilities towards acids and bases show a similar tendency and an ordering can be proposed as: MIL-101(Cr) > NH 2 -UiO-66 > UiO-66 > UiO-67 > NH 2 -MIL-53 > MIL-53(Al)>ZIF-8 > CuBTC > NH 2 -MIL-101(Al). In the tests with H 2 O 2 most materials behaved poorly, only the UiO-66 and NH 2 -UiO-66 frameworks show a good stability.
تدمد: 1387-1811
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::f199a65ed03ec23a47d3577b8f53584a
https://doi.org/10.1016/j.micromeso.2015.11.055
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........f199a65ed03ec23a47d3577b8f53584a
قاعدة البيانات: OpenAIRE