Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized l -aspartic acid and l -glutamic acid in an aqueous phase at room temperature
العنوان: | Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized |
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المؤلفون: | Hongbing Ji, Wu-Bin Yu, Hai-Min Shen, Yuan-Bin She, Wen-Jie Zhou, Qiu-Ping Liu, Hongke Wu, Wang Yan |
المصدر: | New Journal of Chemistry. 40:4874-4878 |
بيانات النشر: | Royal Society of Chemistry (RSC), 2016. |
سنة النشر: | 2016 |
مصطلحات موضوعية: | 010405 organic chemistry, Chemistry, Inorganic chemistry, Aqueous two-phase system, Substrate (chemistry), General Chemistry, Glutamic acid, 010402 general chemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, Contact angle, Metal free, X-ray photoelectron spectroscopy, Materials Chemistry, Selectivity |
الوصف: | L-Aspartic acid and L-glutamic acid were immobilized on hybrid silica and characterized by FT-IR, XPS, contact angle measurements, TGA, SEM and XRD. Employed as heterogeneous catalysts in the selective oxidation of sulfides with 30% H2O2 at room temperature, 99% conversion and 97% selectivity were achieved with excellent substrate tolerance and recyclability. |
تدمد: | 1369-9261 1144-0546 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::f1e3138fce0d98b0ed97aa6dea53283f https://doi.org/10.1039/c6nj00854b |
رقم الأكسشن: | edsair.doi...........f1e3138fce0d98b0ed97aa6dea53283f |
قاعدة البيانات: | OpenAIRE |
تدمد: | 13699261 11440546 |
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