Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized l-aspartic acid and l-glutamic acid in an aqueous phase at room temperature

التفاصيل البيبلوغرافية
العنوان: Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized l-aspartic acid and l-glutamic acid in an aqueous phase at room temperature
المؤلفون: Hongbing Ji, Wu-Bin Yu, Hai-Min Shen, Yuan-Bin She, Wen-Jie Zhou, Qiu-Ping Liu, Hongke Wu, Wang Yan
المصدر: New Journal of Chemistry. 40:4874-4878
بيانات النشر: Royal Society of Chemistry (RSC), 2016.
سنة النشر: 2016
مصطلحات موضوعية: 010405 organic chemistry, Chemistry, Inorganic chemistry, Aqueous two-phase system, Substrate (chemistry), General Chemistry, Glutamic acid, 010402 general chemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, Contact angle, Metal free, X-ray photoelectron spectroscopy, Materials Chemistry, Selectivity
الوصف: L-Aspartic acid and L-glutamic acid were immobilized on hybrid silica and characterized by FT-IR, XPS, contact angle measurements, TGA, SEM and XRD. Employed as heterogeneous catalysts in the selective oxidation of sulfides with 30% H2O2 at room temperature, 99% conversion and 97% selectivity were achieved with excellent substrate tolerance and recyclability.
تدمد: 1369-9261
1144-0546
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::f1e3138fce0d98b0ed97aa6dea53283f
https://doi.org/10.1039/c6nj00854b
رقم الأكسشن: edsair.doi...........f1e3138fce0d98b0ed97aa6dea53283f
قاعدة البيانات: OpenAIRE