Cadmium sulphide nanocrystallites have been synthesized using precipitation method. The average sizes of the prepared samples is determined by XRD (x-ray diffraction) method. Morphological studies are carried out by SEM (scanning electron microscopy) measurement. Necesssary elements present in prepared samples, are confirmed by EDAX (energy dispersive analysis of x-ray spectroscopy) method. By Ultraviolet visible spectroscopy measurement, the value of absorption wavelength, band gap values are calculated in optical method. The electrical properties are analysed using impedance analyser measurement for the Nanocrystallites.