Intrinsic Pseudocapacitive Affinity in Manganese Spinel Ferrite Nanospheres for High-Performance Selective Capacitive Removal of Ca2+ and Mg2+
| العنوان: | Intrinsic Pseudocapacitive Affinity in Manganese Spinel Ferrite Nanospheres for High-Performance Selective Capacitive Removal of Ca2+ and Mg2+ |
|---|---|
| المؤلفون: | Shuhong Xiang, Hongjian Zhou, Yingsheng Xu, Huijun Zhao, Haimin Zhang, Guozhong Wang |
| المصدر: | ACS Applied Materials & Interfaces. 13:38886-38896 |
| بيانات النشر: | American Chemical Society (ACS), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Ionic radius, Materials science, Chemical engineering, chemistry, Capacitive deionization, Solvothermal synthesis, Electrode, chemistry.chemical_element, General Materials Science, Electrolyte, Manganese, Ternary operation, Redox |
| الوصف: | Pseudocapacitor-type hybrid capacitive deionization (PHCDI) has been developed extensively for deionization, which enables to address the worldwide freshwater shortage. However, the exploitation of selective hardness ion removal in resourceful hard water via the intrinsic pseudocapacitive effect, rather than the ion-sieving or ion-swapping effect based on the electric double layer (EDL) of porous carbon, is basically blank and urgent. Herein, manganese spinel ferrite (MFO) nanospheres were successfully fabricated by one-step solvothermal synthesis and used as the cathode for PHCDI assembled with commercial activated carbon. The MFO electrode exhibited prominent capacities of 534.6 μmol g-1 (CaCl2) and 980.4 μmol g-1 (MgCl2), outperforming those of other materials ever reported in the literature. Fascinatingly, systematic investigation of binary and ternary ion solutions showed the high electro-affinity of hardness ions (Ca2+ and Mg2+) toward Na+, especially the leading affinity of Mg2+, in which the superhigh hardness selectivity of 34.76 was achieved in the ternary solution with a molar ratio of Na-Ca-Mg as 20:1:1. Unexpectedly, the ion-swapping trace in a multi-ion environment was also first detected in our pseudocapacitive-based electrode. The electrochemical response in unary and multiple electrolytes disclosed that the unique pseudocapacitive affinity based on the cation (de)intercalation-redox mechanism was from the synergistic effect of the relative redox potential, ionic radius, and valence, in which the redox potential was the dominant factor. |
| تدمد: | 1944-8252 1944-8244 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::f6a9cb04c728e1a4ab4e6eb58a8b56b8 https://doi.org/10.1021/acsami.1c09996 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........f6a9cb04c728e1a4ab4e6eb58a8b56b8 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 19448252 19448244 |
|---|