Ternary Liquid–Liquid Equilibria of Water + Prop-2-enoic Acid + Isobutyl Ethanoate at Different Temperatures
| العنوان: | Ternary Liquid–Liquid Equilibria of Water + Prop-2-enoic Acid + Isobutyl Ethanoate at Different Temperatures |
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| المؤلفون: | Yingming Zhang, Chunshan Zhu, Chen Li, Hongxun Zhang, Lei Zhang |
| المصدر: | Journal of Chemical & Engineering Data. 56:3411-3415 |
| بيانات النشر: | American Chemical Society (ACS), 2011. |
| سنة النشر: | 2011 |
| مصطلحات موضوعية: | Activity coefficient, Aqueous solution, UNIQUAC, Ternary numeral system, Chemistry, General Chemical Engineering, Azeotropic distillation, Non-random two-liquid model, Thermodynamics, General Chemistry, Ternary operation, Phase diagram |
| الوصف: | To screen the proper solvent for separating prop-2-enoic acid aqueous solution by the method of extraction followed by heterogeneous azeotropic distillation, the liquid–liquid equilibria (LLE) data for the ternary system water + prop-2-enoic acid + isobutyl ethanoate at (293.15, 303.15, and 313.15) K were measured at atmospheric pressure. The reliability of the experimental LLE data was ascertained through Othmer–Tobias and Hand correlations. The LLE phase diagrams at different temperatures for the ternary system were given. Distribution coefficients and separation factors were calculated from the LLE data. The thermodynamic models of nonrandom two-liquid (NRTL) and universal quasichemical activity coefficient (UNIQUAC) were used to correlate the data of the ternay system. The calculated values from both models agree well with the experimental values. |
| تدمد: | 1520-5134 0021-9568 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::fae2076a443265675fb855ead7649308 https://doi.org/10.1021/je2003226 |
| رقم الأكسشن: | edsair.doi...........fae2076a443265675fb855ead7649308 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15205134 00219568 |
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