Hydrothermal synthesis, characterization, and the influence of Bi+3 doping over nanocomposite thin films
العنوان: | Hydrothermal synthesis, characterization, and the influence of Bi+3 doping over nanocomposite thin films |
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المؤلفون: | Anirban Dhar, Shailendra Kr. Singh, Mukul Chandra Paul |
المصدر: | Journal of Materials Science: Materials in Electronics. 32:5504-5519 |
بيانات النشر: | Springer Science and Business Media LLC, 2021. |
سنة النشر: | 2021 |
مصطلحات موضوعية: | 010302 applied physics, Nanocomposite, Materials science, Band gap, Doping, Analytical chemistry, Nanoparticle, Conductivity, Condensed Matter Physics, 01 natural sciences, Atomic and Molecular Physics, and Optics, Electronic, Optical and Magnetic Materials, X-ray photoelectron spectroscopy, 0103 physical sciences, Hydrothermal synthesis, Electrical and Electronic Engineering, Fourier transform infrared spectroscopy |
الوصف: | In this study, we report ZnO and Bismuth-doped ZnO (rBi/Zn) (r = 3, 6, 9 wt%) nanoparticles through the hydrothermal synthesis method. Different characterization techniques such as XRD, TGA, FTIR, XPS, FESEM, EDX analysis, UV spectroscopy, and PL spectroscopy have been used to investigate the influence of Bi+3 doping over the synthesized rBi/Zn nanoparticles. XRD result reveals a reduction of average particle size from 30 to 21 nm with the increment of Bi+3 (3 → 9 wt%) concentration. The mass variation in rBi/Zn was found more than the pure ZnO sample which reveals in TGA results. The material rBi/Zn exhibits a single-stage to multi-stage decomposition with the enhancement of Bi+3 (3 → 9 wt%) concentration while the XPS result indicates that the reduction of binding energy with increasing Bi+3 doping. UV analysis shows that as the concentration of Bi+3 increases the band gap of the material rBi/Zn reduces from 3.217 to 2.901 eV. However, the conductivity analysis shows the enhancement in the conductivity of rBi/Zn (0 → 6 wt%) but decreases from 6 → 9 wt%. Furthermore, the morphology of rBi/Zn also changes as the doping of Bi+3 increases which is possibly due to the enhancement of lattice mismatch, and pH variation. Such a kind of rBi/Zn nanocomposite material could be used in optoelectronic devices or fiber optics-based gas-sensing applications. |
تدمد: | 1573-482X 0957-4522 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::fce9a206c453208a43b7f3538d94e7a3 https://doi.org/10.1007/s10854-021-05272-3 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........fce9a206c453208a43b7f3538d94e7a3 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 1573482X 09574522 |
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