High Entropy Perovskite Electrolytes for Reversible Protonic Ceramic Electrochemical Cells
العنوان: | High Entropy Perovskite Electrolytes for Reversible Protonic Ceramic Electrochemical Cells |
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المؤلفون: | Seeun Oh, Dongyeon Kim, Kang Taek Lee |
المصدر: | ECS Transactions. 111:1743-1749 |
بيانات النشر: | The Electrochemical Society, 2023. |
سنة النشر: | 2023 |
مصطلحات موضوعية: | General Medicine |
الوصف: | Reversible protonic ceramic electrochemical cells (R-PCECs) have become the cornerstone of low-temperature solid oxide electrochemical cells (SOCs) below 600 °C. Low activation energy and high energy conversion efficiency are primary significance of R-PCECs. However, electrolytes of high-performance R-PCECs still suffer from poor tolerance to complex operating conditions. To overcome their low stability and enhance proton conductivity, various cations have been doped into the Ba-based perovskite oxide electrolyte. Developing high entropy oxides by introducing multiple metal cations into A- or B- sites of the perovskite structure can be an effective solution for the structural stability. Due to the effect of the entropy-dominated stabilization in multi-doped perovskite oxides, the material can remain single phase under extreme temperatures and chemical environments. Promising high entropy stabilization concepts were adapted to electrolytes, and finally, durable proton-conducting perovskite oxide was designed. Here, we will present our recent progress on development of high entropy perovskite oxide electrolytes for R-PCECs. |
تدمد: | 1938-6737 1938-5862 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::ff4518d6a8cd1e39b4b99326cf8a29bb https://doi.org/10.1149/11106.1743ecst |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........ff4518d6a8cd1e39b4b99326cf8a29bb |
قاعدة البيانات: | OpenAIRE |
تدمد: | 19386737 19385862 |
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