Kinetics of desolvation from crystalline inclusion compounds of a diol host with methanol and ethanol
| العنوان: | Kinetics of desolvation from crystalline inclusion compounds of a diol host with methanol and ethanol |
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| المؤلفون: | Fumio Toda, Bruce M. Oom, Susan A. Bourne |
| المصدر: | Journal of the Chemical Society, Perkin Transactions 2. :585-588 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 1997. |
| سنة النشر: | 1997 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Ethanol, chemistry, Diffusion, Diol, Kinetics, Organic chemistry, Desolvation, Crystal structure, Crystalline inclusion, Methanol |
| الوصف: | The crystal structures of the inclusion compounds of (4R,5R)-4,5-bis(hydroxydiphenylmethyl)-2,2-dimethyl-1 ,3-dioxolane with methanol and ethanol have been elucidated. Their isothermal kinetics of desolvation have been studied. Both lose the guest in a single deceleratory step, and a kinetic model based on a diffusion mechanism was found to be the best description for this process. |
| تدمد: | 1364-5471 0300-9580 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::ff8e0b28f4ea59864c73fe3e66254499 https://doi.org/10.1039/a605298c |
| رقم الأكسشن: | edsair.doi...........ff8e0b28f4ea59864c73fe3e66254499 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 13645471 03009580 |
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