Poly (lactic acid)/D-limonene/ZnO bio-nanocomposites with antimicrobial properties
العنوان: | Poly (lactic acid)/D-limonene/ZnO bio-nanocomposites with antimicrobial properties |
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المؤلفون: | María Teresa Ulloa, Amparo Ribes-Greus, Francesca Antonella Sepúlveda, Daniel Canales, Viviana Moreno-Serna, Lina M Rivas, Oscar Gil-Castell, J. Andrés Ortiz, Francisca Rivera, Carlos Loyo, Rosario Benavente, Paula A. Zapata |
المساهمون: | Fondo Nacional de Desarrollo Científico y Tecnológico (Chile) |
المصدر: | Digital.CSIC. Repositorio Institucional del CSIC instname Sepúlveda, Francesca Antonella Rivera, Francisca Loyo, Carlos Canales, Daniel Moreno-Serna, Viviana Benavente, Rosario Rivas, Lina María Ulloa, María Teresa Gil Castell, O. Ribes Greus, A. Ortiz, J. Andrés Zapata, Paula A. 2021 Poly (lactic acid)/D-limonene/ZnO bio-nanocomposites with antimicrobial properties Journal of Applied Polymer Science 139 4 51542 |
بيانات النشر: | John Wiley & Sons, 2022. |
سنة النشر: | 2022 |
مصطلحات موضوعية: | Solucions polimèriques, Nanocomposite, D limonene, Materials science, Polymers and Plastics, Molding, General Chemistry, Molding (process), Antimicrobial, 02.- Poner fin al hambre, conseguir la seguridad alimentaria y una mejor nutrición, y promover la agricultura sostenible, Surfaces, Coatings and Films, Lactic acid, 12.- Garantizar las pautas de consumo y de producción sostenibles, Biomaterials, chemistry.chemical_compound, Biopolymers and renewable polymers, Differential scanning calorimetry, Chemical engineering, chemistry, MAQUINAS Y MOTORES TERMICOS, Materials Chemistry, 03.- Garantizar una vida saludable y promover el bienestar para todos y todas en todas las edades, Materials |
الوصف: | [EN] Antimicrobial films of poly (lactic acid) (PLA)/D-limonene/zinc oxide (ZnO)-based bio-nanocomposites were prepared via melt compounding and subsequent thermocompression. D-limonene was incorporated at concentrations of 10 or 20 wt%, and ZnO pure nanoparticles and those organically modified with oleic acid (O-ZnO), with an average diameter of 13.5 nm, were included at concentrations of 3, 5, and 8 wt%. The plasticizing effect of D-Limonene was corroborated by a decrease in the glass transition temperature compared to pure PLA. The presence of ZnO and O-ZnO in the PLA matrix promoted a slight increase in the degree of crystallinity due to its nucleant performance. Although ZnO and O-ZnO induced lower thermal stability and slightly decreased microhardness in the composites, excellent antimicrobial performance was demonstrated. Both ZnO and O-ZnO nanocomposites reached 99.9% of effectiveness for nanoparticles content above 5 wt%, regardless of the source of irradiation, D-limonene concentration, and nanoparticle modification. Therefore, these bio-nanocomposites will allow for future advances in sustainable antimicrobial materials for the medical or food packaging fields. DICYT, Grant/Award Number: Project 022041ZR_POSTDOCT; Fondo Nacional de Desarrollo Cientifico y Tecnologico, Grant/Award Numbers: 1170226, 3200296 |
وصف الملف: | application/pdf |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00ebc3b9842d962e1ae24cfb6a919ef0 http://hdl.handle.net/10261/262780 |
حقوق: | OPEN |
رقم الأكسشن: | edsair.doi.dedup.....00ebc3b9842d962e1ae24cfb6a919ef0 |
قاعدة البيانات: | OpenAIRE |
الوصف غير متاح. |