Field-induced single-ion magnet behaviour of a hexacoordinated Co(ii ) complex with easy-axis-type magnetic anisotropy
| العنوان: | Field-induced single-ion magnet behaviour of a hexacoordinated Co( |
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| المؤلفون: | L. D. Popov, Denis V. Korchagin, Yulia P. Tupolova, Sergey M. Aldoshin, K. V. Zakharov, Alexander N. Vasiliev, Valery V. Tkachev, Igor N. Shcherbakov, Vladimir E. Lebedev, Andrei V. Palii |
| المصدر: | Dalton Transactions. 48:6960-6970 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Quantum chemical, chemistry.chemical_classification, Materials science, Condensed matter physics, Single ion, 010405 organic chemistry, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Ion, Coordination complex, Magnetic field, Inorganic Chemistry, symbols.namesake, Magnetic anisotropy, chemistry, Magnet, symbols, Hamiltonian (quantum mechanics) |
| الوصف: | A coordination compound with the composition [CoLCl2]·H2O (L = bis-condensation product of diacetyl and 2-hydrazinyl-4,6-dimethylpyrimidine) was synthesized, in which the Co(II) ion was hexacoordinated. Under applied DC fields, this compound exhibited single-ion magnet behavior. Two relaxation processes were observed when increasing the applied magnetic field from 1000 to 3200 Oe. The first relaxation (high-frequency) was observed both at 1000 Oe and 3200 Oe, while the second relaxation was only registered under a field of 3200 Oe at low frequencies ( |
| تدمد: | 1477-9234 1477-9226 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::058ea9835525f079e6cb3a05428ef8f0 https://doi.org/10.1039/c9dt00770a |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....058ea9835525f079e6cb3a05428ef8f0 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14779234 14779226 |
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