Synthesis of Luminacin D
| العنوان: | Synthesis of Luminacin D |
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| المؤلفون: | Martin E. Maier, Rajamalleswaramma Jogireddy |
| المصدر: | The Journal of Organic Chemistry. 71:6999-7006 |
| بيانات النشر: | American Chemical Society (ACS), 2006. |
| سنة النشر: | 2006 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Aldehydes, Magnetic Resonance Spectroscopy, Stereochemistry, Aryl, Organic Chemistry, Iodide, Chemistry, Organic, Total synthesis, Carbohydrate, Cleavage (embryo), Aldehyde, Silyl ether, chemistry.chemical_compound, chemistry, Aldol reaction, Benzaldehydes, Spiro Compounds |
| الوصف: | The total synthesis of luminacin D (1) is reported on the basis of two aldol reactions to form the carbohydrate sector, aldehyde 30. Reaction of aldehyde 30 with the aryllithium intermediate derived from aryl iodide 38, cleavage of the silyl ether, and oxidation led to keto aldehyde 41. This advanced intermediate could be converted to luminacin 1 and its 6',8'-epimer. |
| تدمد: | 1520-6904 0022-3263 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::065243f186dab02ca6a56cd56a6d807d https://doi.org/10.1021/jo061104g |
| رقم الأكسشن: | edsair.doi.dedup.....065243f186dab02ca6a56cd56a6d807d |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15206904 00223263 |
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