Theoretical and experimental investigation of 13C relayed 2H–2H-COSY 2D experiments: Application to the analysis of weakly aligned solutes
| العنوان: | Theoretical and experimental investigation of 13C relayed 2H–2H-COSY 2D experiments: Application to the analysis of weakly aligned solutes |
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| المؤلفون: | Philippe Lesot, Olivier Lafon |
| المساهمون: | Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Centre National de la Recherche Scientifique (CNRS), Recurrent funding (CNRS and Univ. Paris-Sud) |
| المصدر: | Journal of Magnetic Resonance Journal of Magnetic Resonance, Elsevier, 2005, 174 (2), pp.254-264. ⟨10.1016/j.jmr.2005.02.011⟩ |
| بيانات النشر: | Elsevier BV, 2005. |
| سنة النشر: | 2005 |
| مصطلحات موضوعية: | PBLG, Nuclear and High Energy Physics, Stereochemistry, Biophysics, 010402 general chemistry, 01 natural sciences, Biochemistry, Spectral line, chemistry.chemical_compound, [CHIM.ANAL]Chemical Sciences/Analytical chemistry, Liquid crystal, Molecule, 2D, RQC, Geminal, 010405 organic chemistry, Chemistry, DECADENCY, Deuterium, Condensed Matter Physics, NMR, 0104 chemical sciences, [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry, Heteronuclear molecule, CLC, Physical chemistry, Polypeptide, Nonane, Two-dimensional nuclear magnetic resonance spectroscopy |
| الوصف: | International audience; We describe new NMR 2D experiments denoted DECADENCY for DEuterium CArbon DEuterium Nuclear CorrelationspectroscopY dedicated to the analysis of anisotropic deuterium spectra. They belong to the class of X-relayed Y,Y-COSY 2D experiments that was initially explored in the case of a 1H–X–1H fragment (IX = 1/2) in isotropic medium. DECADENCY 2D experiments permit to correlate the quadrupolar doublets associated with two inequivalent deuterium nuclei in an oriented CD2 fragment through heteronuclear polarization transfers. Two kinds of pulse sequences are described here using either a double INEPT-type or DEPT-type process. DECADENCY 2D experiments provide an interesting alternative to 2H–2H COSY experiments when the geminal 2H–2H total coupling (scalar and dipolar) is null or too small to provide visible cross-correlation peaks. Such a situation is typically observed for geminal deuteriums in prochiral or chiral molecules dissolved in chiral liquid crystals. The efficiency of these techniques is illustrated using dideuterated prochiral molecules, the phenyl[2H2]methanol and the 1-chloro[1-2H2]nonane, both dissolved in organic solutions of poly-gamma-benzyl-L-glutamate. The advantages of each sequence are presented and discussed. It is shown that the relative sign of the quadrupolar doublets can be determined. |
| تدمد: | 1090-7807 1096-0856 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0f2e4f4018389c8b58e2b2542653958c https://doi.org/10.1016/j.jmr.2005.02.011 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....0f2e4f4018389c8b58e2b2542653958c |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10907807 10960856 |
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