Tuning Zn‐Ion Solvation Chemistry with Chelating Ligands toward Stable Aqueous Zn Anodes
| العنوان: | Tuning Zn‐Ion Solvation Chemistry with Chelating Ligands toward Stable Aqueous Zn Anodes |
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| المؤلفون: | Rongwei Meng, Huan Li, Ziyang Lu, Chen Zhang, Zhenxing Wang, Yingxin Liu, Weichao Wang, Guowei Ling, Feiyu Kang, Quan‐Hong Yang |
| المصدر: | Advanced Materials. 34:2200677 |
| بيانات النشر: | Wiley, 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Mechanics of Materials, Mechanical Engineering, General Materials Science |
| الوصف: | Changing the solvation sheath of hydrated Zn ions is an effective strategy to stabilize Zn anodes to obtain a practical aqueous Zn-ion battery. However, key points related to the rational design remain unclear including how the properties of the solvent molecules intrinsically regulate the solvated structure of the Zn ions. This study proposes the use of a stability constant (K), namely, the equilibrium constant of the complexation reaction, as a universal standard to make an accurate selection of ligands in the electrolyte to improve the anode stability. It is found that K greatly impacts the corrosion current density and nucleation overpotential. Following this, ethylene diamine tetraacetic acid with a superhigh K effectively suppresses Zn corrosion and induces uniform Zn-ion deposition. As a result, the anode has an excellent stability of over 3000 h. This work presents a general principle to stabilize anodes by regulating the solvation chemistry, guiding the development of novel electrolytes for sustainable aqueous batteries. |
| تدمد: | 1521-4095 0935-9648 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11b427bc0ca6372561e9380274b1730a https://doi.org/10.1002/adma.202200677 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....11b427bc0ca6372561e9380274b1730a |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15214095 09359648 |
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