Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3
| العنوان: | Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3 |
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| المؤلفون: | Michele Soleilhavoup, Mohand Melaimi, Xingbang Hu, Guy Bertrand, Jiaxiang Chu |
| المصدر: | Angewandte Chemie International Edition. 54:6008-6011 |
| بيانات النشر: | Wiley, 2015. |
| سنة النشر: | 2015 |
| مصطلحات موضوعية: | Denticity, Hydride, Ammonia borane, Inorganic chemistry, General Chemistry, Borane, Borohydride, Catalysis, chemistry.chemical_compound, chemistry, Polymer chemistry, Dehydrogenation, Carbene |
| الوصف: | The first stable copper borohydride complex [(CAAC)CuBH4] [CAAC = cyclic(alkyl)(amino)carbene] bearing a single monodentate ligand was prepared by addition of NaBH4 or BH3NH3 to the corresponding [(CAAC)CuCl] complex. Both complexes are air-stable and promote the catalytic hydrolytic dehydrogenation of ammonia borane. The amount of hydrogen released reaches 2.8 H2/BH3 NH3 with a turnover frequency of 8400 mol H2 molcat(-1) h(-1) at 25 °C. In a fifteen-cycle experiment, the catalyst was reused without any loss of efficiency. |
| تدمد: | 1521-3773 1433-7851 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19d038db6bf646fe47bd986551a3f93a https://doi.org/10.1002/anie.201500224 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....19d038db6bf646fe47bd986551a3f93a |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15213773 14337851 |
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