Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation
العنوان: | Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation |
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المؤلفون: | Yaoyu Liang, Uttam Kumar Das, Jie Luo, Yael Diskin-Posner, Liat Avram, David Milstein |
المصدر: | Journal of the American Chemical Society. 144:19115-19126 |
بيانات النشر: | American Chemical Society (ACS), 2022. |
سنة النشر: | 2022 |
مصطلحات موضوعية: | Colloid and Surface Chemistry, General Chemistry, Biochemistry, Catalysis |
الوصف: | The development of catalysts for environmentally benign organic transformations is a very active area of research. Most of the catalysts reported so far are based on transition-metal complexes. In recent years, examples of catalysis by main-group metal compounds have been reported. Herein, we report a series of magnesium pincer complexes, which were characterized by NMR and X-ray single-crystal diffraction. Reversible activation of H |
تدمد: | 1520-5126 0002-7863 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1a305119794fd512f97b8a4846a0ba3d https://doi.org/10.1021/jacs.2c08491 |
حقوق: | OPEN |
رقم الأكسشن: | edsair.doi.dedup.....1a305119794fd512f97b8a4846a0ba3d |
قاعدة البيانات: | OpenAIRE |
تدمد: | 15205126 00027863 |
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