Atmospheric Plasma Deposited Dense Silica Coatings on Plastics
| العنوان: | Atmospheric Plasma Deposited Dense Silica Coatings on Plastics |
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| المؤلفون: | Geraud Dubois, Marvi A. Matos, Liam S. Cavanaugh Pingree, Alpana N. Ranade, Reinhold H. Dauskardt, Theo J. Frot, Linying Cui |
| المصدر: | ACS Applied Materials & Interfaces. 4:6587-6598 |
| بيانات النشر: | American Chemical Society (ACS), 2012. |
| سنة النشر: | 2012 |
| مصطلحات موضوعية: | Materials science, Silicon, chemistry.chemical_element, Atmospheric-pressure plasma, Substrate (electronics), Adhesion, engineering.material, Boiling point, chemistry.chemical_compound, Coating, chemistry, Chemical engineering, visual_art, engineering, visual_art.visual_art_medium, Organic chemistry, General Materials Science, Methyl methacrylate, Polycarbonate |
| الوصف: | We explore the application of a high-temperature precursor delivery system for depositing high boiling point organosilicate precursors on plastics using atmospheric plasma. Dense silica coatings were deposited on stretched poly(methyl methacrylate), polycarbonate and silicon substrates from the high boiling temperature precursor, 1, 2-bis(triethoxysilyl)ethane, and from two widely used low boiling temperature precursors, tetraethoxysilane and tetramethylcyclotetrasiloxane. The coating deposition rate, molecular network structure, density, Young's modulus and adhesion to plastics exhibited a strong dependence on the precursor delivery temperature and rate, and the functionality and number of silicon atoms in the precursor molecules. The Young's modulus of the coatings ranged from 6 to 34 GPa, depending strongly on the coating density. The adhesion of the coatings to plastics was affected by both the chemical structure of the precursor and the extent of exposure of the plastic substrate to the plasma during the initial stage of deposition. The optimum combinations of Young's modulus and adhesion were achieved with the high boiling point precursor which produced coatings with high Young's modulus and good adhesion compared to commercial polysiloxane hard coatings on plastics. |
| تدمد: | 1944-8252 1944-8244 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a5bfd8aecba54bd6f83b68f081f8494 https://doi.org/10.1021/am301723d |
| رقم الأكسشن: | edsair.doi.dedup.....2a5bfd8aecba54bd6f83b68f081f8494 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 19448252 19448244 |
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