Electrocatalytic oxidative Z/E isomerization of a stilbene favoured by the presence of an electroactive persistent radical
| العنوان: | Electrocatalytic oxidative Z/E isomerization of a stilbene favoured by the presence of an electroactive persistent radical |
|---|---|
| المؤلفون: | Christian Sporer, Paula Mayorga-Burrezo, Jaume Veciana, Núria Crivillers, Klaus Wurst, Nicola Capra, J. Alejandro de Sousa, Concepció Rovira |
| المساهمون: | Ministerio de Ciencia, Innovación y Universidades (España), Generalitat de Catalunya, Ministerio de Economía y Competitividad (España) |
| المصدر: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| بيانات النشر: | Royal Society of Chemistry (UK), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | endocrine system, Photoisomerization, Metals and Alloys, General Chemistry, Oxidative phosphorylation, Medicinal chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, Optical-properties, Cations, Materials Chemistry, Ceramics and Composites, Dimethylamine, Isomerization |
| الوصف: | A push–pull-functionalized stilbene has been prepared, with an electroactive perchlorotriphenylmethyl (PTM) radical and dimethylamine units as electron-withdrawing and -donating moieties, respectively, showing an electrocatalytic redox-induced Z - E isomerization where the open-shell nature of PTM plays a key role in the isomerization ocurrance. This work was supported by the MICIU of Spain (CTQ2016-80030-R and PID2019-111682RB-I00), the Generalitat de Catalunya (2017-SGR-918) and the MINECO (SEV-2015-0496). J. A. de S. is enrolled in the Materials Science PhD program of UAB. J. A. de S. thanks the Spanish Ministry for the FPI fellowship. The authors acknowledge Dr J. Vidal-Galcedo and Dr Vega Lloveras for the ESR measurements. |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2d76fc50dc1835bc1b8b58d60473a0a6 http://hdl.handle.net/10261/233275 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....2d76fc50dc1835bc1b8b58d60473a0a6 |
| قاعدة البيانات: | OpenAIRE |
| الوصف غير متاح. |