Optical chemical sensor of Gd(iii) based on 5-(2′-bromophenyl- azo)-6-hydroxypyrimidine-2,4-dione immobilized on poly(methyl methacrylate) and 2-nitrophenyloctylether matrix
التفاصيل البيبلوغرافية
العنوان:
Optical chemical sensor of Gd(iii) based on 5-(2′-bromophenyl- azo)-6-hydroxypyrimidine-2,4-dione immobilized on poly(methyl methacrylate) and 2-nitrophenyloctylether matrix
A novel optical chemical sensor (optode) was fabricated for the determination of Gadolinium ions. The optical sensor was prepared by incorporating a recently synthesized ionophore, 5-(2'-bromophenylazo)-6-hydroxy pyrimidine-2,4-dione (BPAHPD), and 2-nitrophenyloctylether (NPOE) as a plasticizer in poly(methyl methacrylate) (PMMA) membrane. The color of the sensing membrane in contact with Gd(iii) ions changed from yellow to red-orange due to the adsorption of Gd(iii) with the maximum absorbance (
