Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents
| العنوان: | Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents |
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| المؤلفون: | Antonius Eichhorn, Laura Kuehn, Todd B. Marder, Udo Radius |
| المصدر: | Chem. Commun.. 53:11694-11696 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Carbon atom, 010405 organic chemistry, Metals and Alloys, chemistry.chemical_element, General Chemistry, 010402 general chemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, Reagent, Polymer chemistry, Materials Chemistry, Ceramics and Composites, Single bond, Organic chemistry, Carbene, Carbon, Alkyl |
| الوصف: | We report herein the room temperature insertion of the carbene carbon atom of the cyclic (alkyl)(amino) carbene cAACMe into the B–B single bonds of the diboron(4) compounds B2pin2, B2cat2, B2neop2, and B2eg2 (pin = pinacolato, cat = catecholato, neop = neopentylglycolato, eg = ethyleneglycolato). |
| تدمد: | 1364-548X 1359-7345 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2eec2bca20b3233d9ab8506d3655dc5c https://doi.org/10.1039/c7cc06302d |
| رقم الأكسشن: | edsair.doi.dedup.....2eec2bca20b3233d9ab8506d3655dc5c |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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